Near threshold rotational excitation of molecular ions by electron-impact

New cross sections for the rotational excitation of H$_3^+$ by electrons are calculated {\it ab initio} at low impact energies. The validity of the adiabatic-nuclei-rotation (ANR) approximation, combined with $R$-matrix wavefunctions, is assessed by comparison with rovibrational quantum defect theory calculations based on the treatment of Kokoouline and Greene ({\it Phys. Rev. A} {\bf 68} 012703 2003). Pure ANR excitation cross sections are shown to be accurate down to threshold, except in the presence of large oscillating Rydberg resonances. These resonances occur for transitions with $\Delta J=1$ and are caused by closed channel effects. A simple analytic formula is derived for averaging the rotational probabilities over such resonances in a 3-channel problem. In accord with the Wigner law for an attractive Coulomb field, rotational excitation cross sections are shown to be large and finite at threshold, with a significant but moderate contribution from closed channels.Comment: 3 figures, a5 page

Electron-impact rotational and hyperfine excitation of HCN, HNC, DCN and DNC

Rotational excitation of isotopologues of HCN and HNC by thermal electron-impact is studied using the molecular {\bf R}-matrix method combined with the adiabatic-nuclei-rotation (ANR) approximation. Rate coefficients are obtained for electron temperatures in the range 5$-$6000 K and for transitions among all levels up to J=8. Hyperfine rates are also derived using the infinite-order-sudden (IOS) scaling method. It is shown that the dominant rotational transitions are dipole allowed, that is those for which $\Delta J=1$. The hyperfine propensity rule $\Delta J=\Delta F$ is found to be stronger than in the case of He$-$HCN collisions. For dipole allowed transitions, electron-impact rates are shown to exceed those for excitation of HCN by He atoms by 6 orders of magnitude. As a result, the present rates should be included in any detailed population model of isotopologues of HCN and HNC in sources where the electron fraction is larger than 10$^{-6}$, for example in interstellar shocks and comets.Comment: 12 pages, 4 figures, accepted in MNRAS (2007 september 3

Many parameter Hoelder perturbation of unbounded operators

If $u\mapsto A(u)$ is a $C^{0,\alpha}$-mapping, for $0< \alpha \le 1$, having as values unbounded self-adjoint operators with compact resolvents and common domain of definition, parametrized by $u$ in an (even infinite dimensional) space, then any continuous (in $u$) arrangement of the eigenvalues of $A(u)$ is indeed $C^{0,\alpha}$ in $u$.Comment: LaTeX, 4 pages; The result is generalized from Lipschitz to Hoelder. Title change

Entropy of complex relevant components of Boolean networks

Boolean network models of strongly connected modules are capable of capturing the high regulatory complexity of many biological gene regulatory circuits. We study numerically the previously introduced basin entropy, a parameter for the dynamical uncertainty or information storage capacity of a network as well as the average transient time in random relevant components as a function of their connectivity. We also demonstrate that basin entropy can be estimated from time-series data and is therefore also applicable to non-deterministic networks models.Comment: 8 pages, 6 figure

Discussion on a new model for the Hercynian Orogen of Gondwana France and Iberia by D. Shelley & G. Bossière.

In spite of numerous studies, the geodynamic evolution of the Hercynian Orogeny of Western Europe is still controversial. In a recent paper, Shelley and Bossière (2000) propose that the Hercynian Orogeny in Iberia and France was a ‘collage' of distinct fault-bounded ‘terranes' developed during a major dextral wrenching of more than 2000 km. This interpretation is in line with that already proposed by Badham (1982) but is at variance with most other published models that emphazise tangential tectonics, that is to say thrusting and collision tectonics driven by oceanic and continental subduction (e.g. Matte; Ledru; Dias and Faure and references therein). The Shelley and Bossière model has been criticized for parts dealing with the Iberian branch of the orogen by Pereira and Silva (2001). In the following, we shall comment on the strike-slip model for the S. Armorican branch of the belt, on the basis of first-hand geological data aquired from the SE part of the Armorican Massif ( Cartier and Cartier) and general considerations on the Hercynian Belt